Dibromido(di-2-pyridyl disulfide-κ2 N,N′)zinc(II)
نویسندگان
چکیده
The molecular structure of the title compound, [ZnBr(2)(C(10)H(8)N(2)S(2))], contains a seven-membered chelate ring in which the zinc atom is coordinated by two bromide ions and by the two pyridyl N atoms of a single 2,2'-dipyridyldisulfide (dpds) ligand within a slightly distorted tetra-hedron. As is usual for this type of complex, the disulfide group does not participate in zinc coordination. The chelate complexes are connected via weak inter-molecular C-H⋯Br hydrogen bonding into chains, which extend in the [010] direction.
منابع مشابه
Dibromido(di-2-pyridyl sulfide-κ2 N,N′)zinc(II)
The molecule of the title compound, [ZnBr(2)(C(10)H(8)N(2)S)], contains a six-membered chelate ring in a boat conformation in which the Zn atom is coordinated by two Br atoms and by the two pyridyl N atoms of a single di-2-pyridyl sulfide (dps) ligand within a slightly distorted tetra-hedron. The dihedral angle between the pyridine rings is 52.7 (1)°. As is usual for this type of complex, the s...
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عنوان ژورنال:
دوره 64 شماره
صفحات -
تاریخ انتشار 2007